DEVELOPMENT OF ALKALI-ACTIVATED MORTAR BASED ON DENDÊ BOILER ASH AND WOOD BURNING ACTIVATED WITH SODIUM SILICATE SOLUTION
Alkali-Activation; Mortar; Industrial Ashes; Wastes
Cement-based products are the most widely used building materials in the world and their growing demand and high volume of use have raised discussions about negative environmental impacts and stimulated the search for alternative materials. In this scenario, alkali-activated binders presents interesting characteristics such as the rapid development of high mechanical strength and high chemical stability, being possible to reuse wastes in its formulation, which contributes to the reuse of resources and reduction of various environmental impacts. The present research aimed to develop an alkali-activated mortar based on the mix of palm oil fuel ash and wood ash, residues with high world production, activated with an alternative solution of sodium silicate. The precursor materials were processed through grinding and sieving, and their physical chemical characteristics were evaluated by laser diffraction, x-ray diffraction and fluorescence and thermogravimetry. Six binders were formulated, varying the ash ratio to achieve CaO/SiO2 molar ratios between 0.3 and 1.0 and SiO2/Al2O3 between 8 and 17, fixing the Na2O/SiO2 ratio of the activating solution to 1.40. Two of the developed binders used metakaolin as a complementary source of Al2O3. After evaluating the mechanical properties of the binders, three mortars were developed with 25% and 50% variation in the volumetric aggregate content, observing the influence of this parameter in the development of flexural and compressive strength, water absorption, voids index, specific mass and accelerated efflorescence development. It was concluded that the ashes used are suitable for alkali-activation, which is a potentially beneficial use from both environmental and economic point of view, since such residues have little or no added value and high production volume worldwide, being its alkali
activation a positive way for reuse in the construction industry. Relevant data were also obtained on the theoretical formulation, production process and mechanical characteristics of the alkali-activation of the ash, with the production of binders with full development of resistance within 2 days. It was observed that the high organic matter content of the residues (greater than 30%) hindered the development of mechanical strength of the mixtures, even so, adjustments in the dosage parameters allowed to achieve average flexural strength of 3.54 MPa and compressive strength of 10.5 MPa at 14 days with 25% aggregate by volume, values higher than the requirements of NBR 13281 (2005) for use as laying and covering mortar. In addition, the developed mortars showed low susceptibility to the development of efflorescence, the increase in the aggregate content from 25% to 50% reduced the affected area by 50% and did not change the absorption rate